The Law of Reflection tells us that the angle of incidence of a ray of light equals the angle of reflection of the ray. See the following link:
http://scienceworld.wolfram.com/physics/LawofReflection.html
Let θ = the angle of incidence. By the Law of Reflection, the angle of reflection is also θ.
2θ = 90o
θ = 90o/2
θ = 45o