OK, Sam, d = rt, right?
The first equation, the total distance is 280 km. If a = the rate of car one and b = the rate of car 2,
2a + 2b = 280
Now, in the 2nd scenario, car 2 goes a certain distance, but car 1 goes the entire 280 km plus the extra distance to catch up.
14a = 280 + 14b
Now, "solve" the first equation for a.
2a = 280 - 2b
a = 140 - b
Then substitute this "value" for a into the 2nd equation.
14(140 - b) = 280 + 14b
Solve for b, take what you get and substitute it into the first equation to solve for a.
Hope this helps!