Damilola G.

asked • 01/03/17

Qualitative analysis

A solution of HNO3 contained 0.67g in 100cm3. 31cm3 of this solution neutralised 25cm3 of a solution Na2CO3. Calculate the concentration of the trioxocarbonate (iv) solution 

1 Expert Answer

By:

Michael C. answered • 01/04/17

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Damilola G.


Sir I appreciate.
But I can't understand what you meant by this:

.1mol/Liter (.031Liter) = 3.1 x 10 -3
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01/04/17

Michael C.

No problem.
 
Molarity is defined in units of moles per liter.  So we have 0.1 moles per 1 liter concentration of Nitric Acid (HNO3), which by definition is 0.1 Molar Nitric Acid.
 
The problem says we titrated 31cm3 which is the same as saying 31mL. I just converted 31mL to Liters so it's .031Liters titrated.
 
Then I just multiplied the concentration times the volume to get the number of moles.
 
In this problem, you could have just left the units in mL or even cm3 (which you'll rarely see volume expressed in cubic centimeters) as they cancel out in the equation.  For many problems though, it's good to have a habit of converting to Liters as most problems as for the concentration specifically in molarity, as this is most likely what you'll see the concentration at in lab.
 
I find it's good to express it like this initially for acid-base titration problems to help keep units straight.
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01/04/17

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