From CH4 + 2O2 → CO2 + 2H2O, confirm that there is 1 C on each side of the Reaction Arrow.
Furthermore, note the H4 left of the arrow and the 2H2 right of the arrow, which means that there
are 4 H's on each side of the Reaction Arrow.
With C's and H's balanced or equal on each side of the arrow, note the 2O2 and the O2 + 2O
to count 4 O's before and after the reaction.
Searching for Carbon Dioxide, one sees CO2 once to right of the Reaction Arrow, which can also
be written as "1CO2", meaning "one mole of CO2." There are approximately 6.022 × 1023 CO2
molecules in one mole of Carbon Dioxide (with each molecule containing 1 Carbon atom bonded to
2 Oxygen atoms).