Let V(t) = volume of water in tank as function of time.
a) dV/dt= kV ... rate is proportional to volume ... rearrange to find dV/V=kdt and integrate both sides to find ln(V)=kt+C and V(t)= ekt+C = eCekt. Note that V(0)=200 thus eC=200L and that V(5)= 200*,8=160L =200e5k, thus k= -.0446 min-1. V(t)=200e-.0446t.
b) dV/dt= ktV ... rate is proportional to volume*time. rearrange to find dV/V=ktdt and lnV= .5kt2+C. Find k & C using the initial conditions.