Perpendicular lines intersect at a 90 degree angle. For this to be true, either one line is horizontal (e.g., y = 5) and the other is vertical (e.g., x = 4) or the slopes are negative reciprocals of each other (e.g., 3 and -1/3).
y = 2x and y = 3x intersect at the origin. (In both cases, if x = 0, then y = 0.) The slopes are not negative reciprocals, so these lines are not perpendicular.
The second pair of equations can be rewritten in slope-intercept form as y = -6x + 16 and y = 5x + 20. The slopes are not equal, so we know the lines are not parallel and intersect somewhere. Ther slopes are not negative reciprocals, so we know they are not perpendicular. The solution is (-4/11, 200/11).