Hello, Vian,
Styart by calculating the number of moles of both reactants. Divide their masses by their molar masses:
SiO2: (92 grams)/(60.1 grams/mole) = 1.53 moles SiO2
HF: (48 grams)/(20.0 grams/mole) = 2.40 moles HF
The balanced equation says we need 4 moles of HF for every 1 mole SiO2, a molar ratio of 4 to 1. Since we have 1.53 moles of SiO2, four times that amount will exceed the amount of HF that would be needed to completely react. SiO2 is therefore the limiting reagent. When all 2.40 moles of HF are reacted, they will have consumed (2.40 moles/4) = 0.60 moles of SiO2. That will leave behind (1.53 - 0.931 = 0.931 moles of SiO2. Multiply by the molar mass of SiO2 to find grams left behind (0.931 moles)*(60.1 grams/mole) = 55.9 grams SiO2 , left sitting in the beaker.
The equation says we'll obtain 1 mole of SiF4 for each mole of SiO2 consumed (or 1/4 of the moles consumed of HF). That gives us 0.600 moles of SiF4. That means we'll have (0.60 moles)*(159.4 grams/mole) = 62.4 grams of SiF4.
Bob