For the roots to be real, the part under the radical in the quadratic formula -- b squared minus 4 times a times c -- must not be negative. Here b=6, a=1 and c=k. So:
36 - 4k ≥ 0
36 ≥ 4k
9 ≥ k
So the largest possible value of k for which the roots will be real is 9.