Draw right triangle ABC with acute angle A and right angle C. Let a = side opposite angle A, b = side opposite angle B and c = hypotenuse.
Then sinA = a/c and cosA = b/c
So, sinA + cosA = a/c + b/c = (a+b) / c.
In any triangle, the sum of the lengths of any two sides must be greater than the length of the third side.
So, (a+b) / c > 1.
Therefore, if A is an acute angle, then sinA + cosA > 1.
The inequality is not valid for all angles, as Arturo illustrated in his answer.