the molar mass of barium chloride is 208.23 g/mol, meaning that
moles = 0.125 g / 208.23 = 0.0006 mol
from there then you can divide by the given Molarity to find the Volume
Volume = Moles / Molarity
Volume = 0.0006 mol / (0.100 mol/L) = 0.006 L = 6.00 mL