71g - 35.07g = 35.93 g of oxygen
Percent composition is:
Phosphorus: 35.07/71= 49.4%
Oxygen: 35.93/71 = 50.6%
Find the number of moles of phosphorus and oxygen
phosphorous : 35.07g / 31 g/mol = 1.13 mol
oxygen : 35.93 / 16g/mol = 2.25 mol
divide by the smallest:
1.13/1.13 = 1
2.25/1.13= 2
Empirical formula is: PO2