STEP 1:
Sodium is an alkali METAL with a +1 charge.
OXIDE is an anion with a -2 charge.
You should memorize the charges (common oxidation states) by looking at the families on the periodic table. (:
So, if it's Na+1 with O-2, we criss-cross the charges to get the sub-scripts. So we get Na2O.
STEP 2:
Water is H2O, as I am sure you know. So we are done with the reactant's side: Na2O + H2O
STEP 3:
So, here's where the fun part comes in. You need to memorize various types of reactions. One type is ANY METAL OXIDE ADDED TO WATER MAKES A STRONG BASE. The moment you saw sodium METAL and the OXIDE anion, your brain should go "ding! ding!" (I suggest making flashcards of the various types of reactions in your book) and you should think...IT MAKES A STRONG BASE!
STEP 4:
To write the base, you put Na+1 with a HYDROXIDE anion (OH-) which you need to also memorize.
So, Na+ and OH- cancel their charges and you simply get NaOH.
STEP 5:
We're not done yet. You have to BALANCE the final equation. We have Na2O + H2O --> NaOH. We have 2 sodiums and 2 oxygens and 2 hydrogens on the left side, but only one of each on the right side. So we have to multiply the entire right species by a coefficient of 2.
FINAL ANSWER:
Na2O + H2O --> 2NaOH
Hope this helps!! I used to help my students online all the time.
Mathalina S.
08/03/15