Even though they are pulled out simultaneously we can think of it sequentially
P(first marble is green) = 3/6
P(2nd marble is green) = 2/5 -- 2 green left and 5 total left after the first marble is chosen
so p = 3/6 * 2/5 = 1/5
If you are comfortable with the combination function (which you really want to be!). You can get the answer this way:
p = C(3,2) / C(6,2)