I am not an astronomer, but I believe this problem could be solved using proportions.
Every 32 min (5:57am – 5:25am = 6:29am – 5:57am = 32 min) the twilight changes by 6°
At 5:25am it was 18°, at 5:57am it was 12°.
Let 5:25am be the initial moment. In 32 min the twilight changes by 18° - 12° = 6°.
In what time t (from 5:25am) the twilight will change to 16.1° (in other words, changes by
18° - 16.1° = 1.9°)?
Make proportion: 32 / 6 = t / 1.9
Solve it: t = 32(1.9)/6
If you want to find the time in seconds, it is convenient to find solution as a mixed number:
t = 32(19/10)/6 = (32•19) / (10•6) = 608/60 = 10 and 8/60, or 10 min 8 sec.
So, the twilight will be 16.1° at 5:25am + 10 min 8 sec = 5:35:08am.