Let x be the length of each side of the base. Let h be the heigh of the box. (x, h > 0)
The surface area is A = 2x2 + 4hx = 100. So h = (50 - x2)/ 2x.
The volume of the box is V = x2h = x2(50 - x2)/ 2x = x(50 - x2)/2 = 25x - x3/2.
V'(x) = 25 - 3x2/2.
V'(x) = 0 when x = (5√6)/3 (since x > 0).
Since V'(x) > 0 for 0 < x < (5√6)/3 and V'(x) < 0 for x > (5√6)/3, V(x) is maximum when x = (5√6)/3.
So, h = (50 - ((5√6)/3)2)/(2(5√6)/3) = (5√6)/3 = x.
Thus, dimensions will maximize the volume are ((5√6)/3)·((5√6)/3)·((5√6)/3)