2·(12+10.6+8.8+8+6) = 90.8 gallons
(Notice the 5 y-values of the rate of change function are used as 5 heights of the rectangles -- the y-value r(10) = 4.8 is NOT used because the left-hand Riemann sum ignores f(b).)
You might consider the following question: Which one word in the question guarantees that this approximation will be the overestimate asked for?