Draw a figure.
Lots of arithmetic needed here, but the "math" is as follows:
Let L be the horizontal distance from the attachment point.
Because the line is assumed parallel to the surface, the angle θ you want to find is such that
tan θ = 75/L i.e.
θ=arctan (75/L
dθ/dt = L2/(752 + L2) (dL/dt)...you know that DL/dt is 2 ft/sec
The only other thing you need is what is L when 250 of line is out. That can be obtained from the Pythagorean Theorem: sqrt(2502 - 752)