From ex = 3 − 2x, form the equation 3 − 2x − ex = 0.
A Casio Graphing Calculator shows no breaks or discontinuities in y = 3 − 2x − ex for 0 ≤ x ≤ 1. Also, y(0) = 2 and y(1) = -1.718281828. The Intermediate Value Theorem states that there is at least one value of x (call it "c") for 0 ≤ x ≤ 1 that will satisfy y(c) = 0 which does fall between y(0) = 2 and
y(1) = -1.718281828.
Computing more and more accurate values of x by Newton's Method For Approximation Of Equation Roots (starting with x = 0.5) and re-feeding each succeeding value of x into the formula
x − (3 − 2x − ex)/(-2 − ex) [x minus the ratio f(x)/f'(x) where f(x) = (3 − 2x − ex) and f'(x) = (-2 − ex)]
until the value of x stops changing will confirm that there is a highly accurate root of 3 − 2x − ex = 0 at
x = 0.5942049585 which is in the domain of 0 ≤ x ≤ 1.