Twice as likely means an odds ratio of 2:1 which is equivalent to the probability of 2/3.
Twice as likely means that there will be 2 male babies for every 1 female...so out of 3 babies, 2 will be male, i.e. probability of 2/3.
Please note that what I have written is an approximation of the law of large numbers about which you might want to read!