Hello, thank you for taking the time to post your question!
The key on this type of question is to find a way to relate the variables to one another. On this one we have
x + y = 721.8 because the sum between them is 721.8
x = y + 10.2 because the speed of the first train is 10.2 mph faster
from there then I would plug in the second equation into the first and then solve algebraically
y + 10.2 + y = 721.8
2y = 711.6
y = 355.8
meaning that x = 355.8 + 10.2 = 366
so the speed of the first train is 366 mph and the speed of the second train is 355.8 mph
I hope that helps you get moving in a better direction on this type of question! Feel free to reach out if you have any additional questions beyond that :)