Hello, thank you for taking the time to post your question!
There are (3 + 2 + 1) = 6 total choices, of which 2 are advertisements, so you want to take
2 / (3 + 2 + 1) = 2/6 = 1/3
Meaning the probability that an advertisement is opened first is 1/3
I hope that helps you get moving in a better direction on this type of question! Feel free to reach out if you have any additional questions beyond that :)