A straight flush is 5 cards of any of 4 suits in sequential order. The ace can be considered high or low. There are 52 cards in a deck. The number of possibilities of drawing 5 cards from the deck are C52,5 = 52*51*50*49*48/5! = 2,598,960. There are 10 possible ways for each suit to get a sequence of 5 consecutive cards. For example, AKQJ10, 5432A, 98765, etc. So with 10 ways and 4 suits this is 4* 10 = 40.
The probability of a straight flush = 40/2,598,960 = 0.000015. This assumes you are talking about a 5 card flush, not each hand of 13 cards all having the same suit.