Richard P. answered 10/12/15
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PhD in Physics with 10+ years tutoring experience in STEM subjects
You are on the right track.
r sin(θ) = r cos(θ) then divide both sides by r to get
sin(θ) = cos(θ) the solution to this is θ = pi/4 ( 45 °)
Straight lines passing through the origin (as is the case here) have very simple polar equations:
θ = arctan(m) where m is the slope of the line. Here m = 1 so θ = pi/4