f(t) = 4sec(3t - 6π) = 4/cos(3t - 6π)
I am not sure what is meant by the "beginning of a sample period". If you mean a point where cos(3t - 6π) achieves its maximum, then the maximum value occurs when cos(3t - 6π) = 1. One possibility would be 3t - 6π = 0. So, t = 2π.