Potassium floats off as a separate ion. Silver cation makes partially covalent bond with negative carbon, leaving the nitrogen to be more nucleophilic.
Why do SN2 reactions of alkyl halides proceed differently with KCN and AgCN?
Alkyl halides react with $\\ce{KCN}$ to form alkyl cyanides as the main product, whereas the use of $\\ce{AgCN}$ leads to isocyanides as the chief product. Why does this happen?
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