There are a few things you can do.
1) do not play strings and such as you would pads. Play each note individually as if you are the section. If you are a good enough player, don't quantize if possible. Everyone plays their part with subtle nuance and dynamics differences
2) use your mod wheel on your controller to add swells and decays and subtle volume changes within your sections or parts
3) I've used Garitan before. It's an ok entry level software but for really good sounding orchestral instruments a better library with a multitude of articulations will serve you better if you can afford it
4) make sure you have a thorough understanding of the orchestra and how each instrument interacts with others
Follow a few of these and you should see an improvement in your mock ups