If the other vinegar is pure vinegar that means that it would be 100% concentration. That means that the expression you can set up to model this situation is
0.10(20) + 1.00(x) = 0.25 * (20 + x)
Solving that for the value of x yields
2 + x = 5 + 0.25x
0.75x = 3
x = 4
so you would need to add 4 mL of pure vinegar to get this to balance out
I hope that helps! Feel free to reach out via message for a lesson if you have any additional questions beyond that! :)