Jon P. answered 08/19/15
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First calculate how many different 13-card hands there are when taken from 4 decks. In 4 decks there are 4 x 52 = 208 cards. So the number of different 13 card hands is 13C208. Let's leave it this way for now.
Now, how many of these hands will have exactly 2 black queens?
We know that each deck has 4 queens, of which 2 are black, so there are 8 black queens in 208 cards, and 200 cards that are not black queens.
2 of the cards in our 13-card hands have to be black queens, so there are 2C8 ways to get 2 black queens. And the rest of the cards in the hands, 11, have to be not black queens, so there are 11C200 ways to get 11 cards that are not black queens.
So there are a total of 2C8 * 11C200 ways to get exactly 2 black queens in 13 cards. So to find the probability of exactly 2 black queens, we just divide this by the total number of possible hands, 13C208.
2C8 * 11C200 / 13C208 =
(8! / 2! 6!) (200! / 11! 189!) / (208! / 13! 195!) =
28 * 387790074428411200 / 149389005978091284720 = 0.0727 = 7.27%