Megan F. answered 11/16/21
Cheery math tutor/chemistry teacher | 15+ years | Chemistry PhD
For this problem, you want to first make sure you convert from km to meters, keeping in mind that there are 1000 m in 1 km: 0.250 km (1000 m / 1 km) = 250. m
Then you can use the equation E = hc/λ (where E is the energy, h is Planck's constant, c is the speed of light, and λ is the wavelength in m): E = ((6.626 x 10-34J*s) * (2.998 x 108m/s)) / (250. m) = J/photon
After that, you will convert from J/photon (the energy you will calculate above will be in J/photon as we are calculating from wavelength, and the wavelength of each individual photon due to light being quantized) using Avogadro's number: J/photon (6.022 x 1023 photon / 1 mol) = J/mol
You should get values on the order of 10-28 J/photon and 10-4 J/mol, respectively with 3 significant figures. Hope that helps.