Hello, Janet,
Molar, M, is defined as "moles/liter." A 1 M solution of NaOH has 1 mole of NaOH per every 1 liter (1,000 ml) of solvent, water. To answer this question, rely on the units to guide your calculation. 0.220M NaOH can be rewritten as 0.220moles NaOH/1,000 ml soultion. 32.0 ml would therefore contain:
(32.0 ml)*(0.220moles NaOH/1,000 ml) = 0.00704 moles of NaOH, to 3 sig figs.
Bob