
Stanton D. answered 01/23/21
Tutor to Pique Your Sciences Interest
Hi Will E.,
First of all, you should be aware that included images such as you furnished for these three problems are not openable by your prospective tutor helpers.
The first problem is therefore the only one attackable here.
Depending on the mechanism, the phenyl ring carbons or the alkane positions, may all be attacked by a bromination.
That covers a real mess of products! If Br #2 adds to the C with Br#1 on, that wouldn''t be optically active. And one of the two isomers for attack at the other alkane carbon will be optically active (R, R'); the other (R,S) won't be. The various brominations at the phenyl carbons won't affect the existing optical properties, since these attacks result in brominated phenyl positions, not breaking the resonance of the ring.
Hope that helps you ----
-- Cheers, --Mr. d.