Kyle H. answered 08/22/19
Masters graduate in chemistry with two years of teaching experience
Dichloromethane has two polar bonds and two nonpolar bonds. Trichloromethane has three polar bonds and only one nonpolar bond. Because trichloromethane has less electron density in nonpolar bonds and more electron density in polar bonds, it has a larger dipole moment. Keep in mind this is only true because their polar bonds do not offset