The measures of complementary angles must add up to 90 degrees. So if we let the measure of one angle be x, then the measure of its complement is 90 - x.
Let's say that the measure of the angle measuring (90 - x) is equal to 2 degrees less than 3x the measure of the second. Algebraically, this would be represented as:
90 - x = 3x - 2
90 = 4x - 2
92 = 4x
x = 23
One angle is 23°, and its complement is 90 - 23 = 67°.