
Michael P. answered 02/24/18
Tutor
New to Wyzant
Quick Answers to Math, Chemistry, and Physics Problems
Provide overall volumetric flow balance around the tank: Flow In - Flow Out = Accumulation
In: 5 L salt/min + 10 L salt/min
Out: 15 L salt/min
Accum: 0 since In flow = Out Flow
therefore, the water or salt solution in the tank is kept at a constant volume, V = 100 L (given)
Since the salt concentration in the tank is changing with time until steady state is reached, you want to
solve for the salt concentration in the tank with time. Then you can multiply the salt concentration by the
constant tank volume of water or salt solution to determine the salt mass as a function of time, S(t).
Therefore, provide a salt mass balance around the tank in terms of salt concentration (since it is changing with time):
Let C = salt concentration (kg salt/L) in tank at time, t (well-mixed)
C0 = 0 kg/L (no salt in tank at t = 0 because it is initially fresh water in tank)
In: (0.02 kg salt/L)*(5 L/min) + (0.09 kg salt/L)*(10 L/min)
Out: C*(15 L/min)
Accum: V*dC/dt (remember V is constant at 100 L)
Therefore: V*dC/dt = (0.10 kg salt/min + 0.9 kg salt/min) - C*(15 L/min)
or 100*dC/dt = 1.0 - 15*C (separate variables)
dC/(1 - 15*C) = 0.01*dt (integrate both sides)
∫dC/(1 - 15*C) = 0.01∫dt
-(1/15)[ln(1 - 15*C)/(1 - 15*C0)] = t ( C0 = 0 and multiply both sides by -15 )
[ln(1 - 15*C)] = -15*t
take exponential of both sides and solve for C:
(1 - 15*C)) = e-15*t
(1 - 15*C) = e-15*t
1 - e-15*t = 15*C
C = (1 - e-15*t)/15 ≡ kg salt/L
therefore, S(t) = V*C(t) = (100 L)*C(t) = 100*[1 - e-15*t]/15 = 6.67*[1 - e-15*t]
1a) S(t) = 6.67*[1 - e-15*t]
1b) for 4 hrs, t = 4*60 min = 240 min
S(240) = 6.67*[1 - e-15*240] = 6.67 kg salt (it has long reached steady-state)
2) Since the In volume rate > Out volume rate then the tank volume, V, will change, along with the salt concentration;
therefore, you need to solve for both the V(t) and C(t) to combine to obtain the mass of salt in the tank at time, t
y(t) = V(t)*C(t)
First solve for the volume of brine or water in tank at time, t
dV/dt = 6 L/min - 4 L/min = 2 L/min
∫dV = 2∫dt
V - V0 = 2*t
V(t) = V0 + 2*t ≡ L brine solution or water
C0 = 0 kg salt/L (only water in tank at t = 0)
Now perform a salt mass balance around tank volume:
In: (0.2 kg salt/L)*(6 L/min) ≡ kg salt/min
Out: C*(4 L/min) ≡ kg salt/min
Accum: d(V*C)/dt use chain rule: = V*dC/dt + C*dV/dt ≡ kg salt/min
Out: C*(4 L/min) ≡ kg salt/min
Accum: d(V*C)/dt use chain rule: = V*dC/dt + C*dV/dt ≡ kg salt/min
V*dC/dt + C*dV/dt = 1.2 - 4*C
Note: dV/dt = 2 L/min and V =V0 + 2*t = 100 + 2*t
(100 + 2*t)*dC/dt + 2*C = 1.2 - 4*C (combine like terms and solve for C)
(100 + 2*t)dC/dt = 1.2 - 6*C (divide all terms by 2)
(50 + t)*dC/dt = 0.6 - 3*C (separate variables)
dC/(0.6 - 3*C) = dt/(50 + t) (integrate both sides)
∫dC/(0.6 - 3*C) = ∫dt/(50 + t)
-(1/3)*ln[(0.6 - 3*C)/(0.6 - 3*C0)] = ln[(50 + t)/(50 + t0)] Note: C0 = 0 t0 = 0
ln[(0.6 - 3*C)/(0.6)] = -3*ln[(50 + t)/(50)]
ln(1 - 5*C) = -3*ln(1 + 0.02*t) (take exponential both sides)
1 - 5*C = (1 + 0.02*t)-3
1 - (1+ 0.02*t)-3 = 5*C
5*C = 1 - (1 + 0.02*t)-3
C = 0.2*[1 - (1 + 0.02*t)-3] ≡ kg salt/L
Therefore,
y(t) = V(t)*C(t) = 0.4*(50 + t)*[1 - (1 + 0.02*t)-3]
2 a) y(t) = 0.4*(50 + t)*[1 - (1 + 0.02*t)-3] ≡ kg salt
at t = 50 min
y(50) = 0.4*(50 + 50)*[1 - (1 + 0.02*50)-3] = 35 kg salt