
Michael P. answered 02/26/18
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Let V0 = initial volume of a salt solution = 10 L sol'n
Find the solution volume in the container (V) at a function of time, t (min): Note: in - out = accumulation
in: 3 L/min
out: 2 L/min
Accum: dV/dt
dV/dt = 3 L/min - 2 L/min = 1 L/min (integrate both sides)
∫dV/dt = (1 L/min) ∫dt
V - V0 = t or V(t) = V0 + (1 L/min)* t where: V0 = 10 L salt solution
t = time water flows into container (min)
Now need mass salt balance: S(t) = C(t)*V(t) where: S(t) = mass of salt in container at t (g salt)
C(t) = salt concentration in container at t (g salt/L sol'n)
V(t) = V0 + 1*t (solved above) (L sol'n)
Let: C = salt concentration in container at t, (g salt/L sol'n)
C0 = initial salt concentration in container at t = 0 (g salt/L sol'n) - need to solve for C0
in: 0 (no salt flows into container - only pure water)
out: C*(2 L/min)
accumulation: d(V*C)/dt use chain rule: V*dC/dt + C*dV/dt
V*dC/dt + C*dV/dt = 0 - 2*C note: dV/dt = 1 (from earlier balance) and V = V0 + 1*t (see above)
(V0 + 1*t)*dC/dt + 1*C = - 2*C (separate variables and solve for C)
dC/C = - 3*dt/(V0 + 1*t) (integrate both sides)
ln(C) = -3*ln(V0 + 1*t) (from C = C0 to C and t = 0 to t)
ln(C/C0) = -3*ln[(V0 + 1*t)/V0] (take exponential both sides)
C/C0 = [(V0 + 1*t)/V0]-3 (rearrange)
C0/C = [(V0 + 1*t)/V0]3 (solve for C0) Note: C = 0.2 g/L at t = 5 min
C0 = C*[(V0 + 1*t)/V0]3 (insert given values)
C0 = (0.2 g/L)*{[(10 L + (1 L/min)*(5 min)]/10 L}3
C0 = (0.2 g/L)*3.375 = 0.675 g/L (initial salt concentration in container)
a) S(t = 0) = C(0)*V(0) = C0*V0 = (0.675 g/L)*(10 L) = 6.75 g salt initially in container
For part b) question, you need the time when the salt concentration, C(t=?), is equal to 0.1 g/L then plug that time, t. into volume equation, V(t) = V0 + 1*t, to solve for solution volume in the container at time, t:
C/C0 = [(V0 + 1*t)/V0]-3 (start with this equation from above and solve for t)
[(V0 + 1*t)/V0]3 = C0/C
[(V0 + 1*t)/V0] = (C0/C)1/3
V0 + 1*t = V0*(C0/C)1/3
t = [V0*(C0/C)1/3 - V0]/(1 L/min) = [10 L*(0.675/0.1)1/3 - 10 L]/(1 L/min) = 8.8988 = 8.9 min
Therefore, insert t = 8.9 min into V(t=8.9 min)
V (8.9 min) = V0 + 1* t = 10 L + (1 L/min)*(8.9 min) = 18.9 L salt solution in container when C = 0.1 g/L
b) V = 18.9 L