Brian W. answered 06/04/15
Tutor
New to Wyzant
Let's make Chemistry, Biochemistry, or Spanish not so scary.
Let me know if this answer doesn't make sense. So If you start out with the acetate ion with the first carbon bonded to the second carbon, which is double bonded to an O and single bonded to an O, you'll see you have a lone pair on the O that can form a bond with carbon 2. When you do that, you must push one of the bonds in the C=O up making an extra lone pair on the other O. These are the two structures you talk about in your question. You cant have your third one, because it would require that one of your oxygen atoms only has 6 electrons. Oxygen will NOT go without a complete octet while an adjacent carbon contains an extra lone pair of electrons. Oxygen is strongly electronegative and will pul those electrons back in a heartbeat. Thus, that structure is essentially nonexistant.