Steve C. answered 05/31/15
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Steve C. Math & Chemistry Tutoring
The amount of base present at start is (25 mL)(0.23 M) = 5.75 mmoles
The amount of acid added is (25 mL)(0.25 M) = 6.25 mmoles
After the two solutions are mixed, the pH will be governed by the amount of excess H+, which is 0.5 mmoles/(50 mL) = 0.01 M. The pH of the solution will be -log(.01) = 2
The Kb value for ammonium hydroxide is not needed to answer this problem.