
Robert W. answered 12/03/20
Independent Multi-genre Songwriter with 25+ Years Experience
The links to the files you provided have expired, so I'm flying a little blind on this one, but I'll do my best to answer in general terms to help you out a bit.
The most important thing you can do is to know what your harmonic structure is. Composing voice harmonies without knowing what the underlying chords are can result in some interesting and satisfying effects, but if it's only ever going to be performed a capella, then you'll want to make note of what the accompaniment chords are and where/when those chords change.
The great part is that you said you already play guitar, and have experience harmonizing for two voices. The guitar can naturally harmonize for as many as 6 voices, so if you want your sections to sing the basic triad as well as a few color notes, you can incorporate those into a single guitar chord to see how it sounds and if it's the direction you want to take.
The thing to remember about any voice harmonizing (whether it's for two voices or twelve) is to follow good voice-leading practice. Don't make leaps and jumps unnecessarily complex, try not to cross parts, maintain common tones as much as possible from one chord to the next, and have fun with chord inversions. Trust me, as a choral Bass, we do enjoy singing notes other than the root. :)