J.R. S. answered 05/06/17
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Looking at sodium chloride, NaCl, for every mole of NaCl there are Avogadro's number of formula units (molecules). So the number of formula units of NaCl (molecules) in 3.2 moles = 3.2 moles x 6.02x1023 form.units/mole = 1.93x1024 formula units (molecules).
Now, each molecule (formula unit) contains 1 atom of Na+ and 1 atom of Cl-, for a total of 2 atoms/formula unit. So, total number of atoms is 1.93x1024 formula units x 2 atoms/formula unit = 3.86x1024 atoms