Hello Hailey, I'm going to assume you meant 15 moles.
For an ideal gas, we use PV = nRT
For a real gas such as methane, we use:
[P+a(n/V)2][(V/n) - b] = RT
Plug in all the values:
n = 15,
R = 0.082056
T = 21 + 273
V = 7
Your Pressure, P should be in units of atm.
After you calculate P for each equation, find the difference between them.