Miles,
The number of employees involved doesn't actually matter.
And lets assume we are only dealing with employees who could be administered the tests...i.e. the 25k.
Lets assume the allotments are set at the beginning of the year and we wish to find the answer to the question based on the elapse of one year.
Being chosen for drug testing or alcohol testing are independent events if the employees are picked randomly.
So the probability of being chosen for both during the whole year is .25*.1=.025
Now if we have assigned the drug testing of this individual to a particular quarter, the probability that this quarter independently is picked for alcohol testing is 1/4=.25
So the chances you are looking for are .025*.25=.00625...less than 1 pct.
In the question I would change "one employee" to "a given or particular employee"
Now there are other ways to interpret this question..."of at least one"..."of only one" which are much harder
problems that do require the number of employees involved to solve.